TY - JOUR U1 - Zeitschriftenartikel, wissenschaftlich - begutachtet (reviewed) A1 - Rech, Julian A1 - Ramakers-van Dorp, Esther A1 - Möginger, Bernhard A1 - Hausnerova, Berenika T1 - Modeling of Creep Behavior of Particulate Composites with Focus on Interfacial Adhesion Effect JF - International Journal of Molecular Sciences N2 - Evaluation of creep compliance of particulate composites using empirical models always provides parameters depending on initial stress and material composition. The effort spent to connect model parameters with physical properties has not resulted in success yet. Further, during the creep, delamination between matrix and filler may occur depending on time and initial stress, reducing an interface adhesion and load transfer to filler particles. In this paper, the creep compliance curves of glass beads reinforced poly(butylene terephthalate) composites were fitted with Burgers and Findley models providing different sets of time-dependent model parameters for each initial stress. Despite the finding that the Findley model performs well in a primary creep, the Burgers model is more suitable if secondary creep comes into play; they allow only for a qualitative prediction of creep behavior because the interface adhesion and its time dependency is an implicit, hidden parameter. As Young’s modulus is a parameter of these models (and the majority of other creep models), it was selected to be introduced as a filler content-dependent parameter with the help of the cube in cube elementary volume approach of Paul. The analysis led to the time-dependent creep compliance that depends only on the time-dependent creep of the matrix and the normalized particle distance (or the filler volume content), and it allowed accounting for the adhesion effect. Comparison with the experimental data confirmed that the elementary volume-based creep compliance function can be used to predict the realistic creep behavior of particulate composites. KW - adhesion factor KW - cube in cube model KW - modeling KW - creep compliance KW - particulate composite KW - creep KW - elementary volume UN - https://nbn-resolving.org/urn:nbn:de:hbz:1044-opus-65186 SN - 1422-0067 SS - 1422-0067 U6 - https://doi.org/10.3390/ijms232214120 DO - https://doi.org/10.3390/ijms232214120 PM - 36430596 VL - 23 IS - 22 SP - 13 S1 - 13 PB - MDPI ER -