Processed-Induced Thermal and Viscoelastic Behavior of Extrusion Blow Molded Parts

  • Process-dependent thermo-mechanical viscoelastic properties and the corresponding morphology of HDPE extrusion blow molded (EBM) parts were investigated. Evaluation of bulk data showed that flow direction, draw ratio, and mold temperature influence the viscoelastic behavior significantly in certain temperature ranges. Flow induced orientations due to higher draw ratio and higher mold temperature lead to higher crystallinities. To determine the local viscoelastic properties, a new microindentation system was developed by merging indentation with dynamic mechanical analysis. The local process-structure-property relationship of EBM parts showed that the cross-sectional temperature distribution is clearly reflected by local crystallinities and local complex moduli. Additionally, a model to calculate three-dimensional anisotropic coefficients of thermal expansion as a function of the process dependent crystallinity was developed based on an elementary volume unit cell with stacked layers of amorphous phase and crystalline lamellae. Good agreement of the predicted thermal expansion coefficients with measured ones was found up to a temperature of 70 °C.

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Metadaten
Document Type:Doctoral Thesis
Language:English
Author:Esther Ramakers-van Dorp
Pagenumber:64
ISBN:978-80-7454-892-5
Handle:http://hdl.handle.net/10563/45890
Referee:Berenika Hausnerová
Place of publication:Zlín
Date of final exam:2019/12/12
Contributing Corporation:Tomas Bata University
Date of first publication:2020/01/09
Tag:bulk and local viscoelastic properties; coefficient of thermal expansion; extrusion blow molding; microindentation; processing-structure-property relationship
Departments, institutes and facilities:Fachbereich Angewandte Naturwissenschaften
Institut für Technik, Ressourcenschonung und Energieeffizienz (TREE)
Graduierteninstitut
Dewey Decimal Classification (DDC):6 Technik, Medizin, angewandte Wissenschaften / 66 Chemische Verfahrenstechnik / 660 Chemische Verfahrenstechnik
Entry in this database:2020/02/05