Open Access

In recent years, a plethora of high spectral resolution observations of sub-mm and FIR transitions of methylidene (CH), have demonstrated this radical to be a valuable proxy for H2, that can be used for characterising molecular gas within the interstellar medium (ISM) on a Galactic scale, including the CO-dark component. Here we report the discovery of the 13CH isotopologue in the ISM using the upGREAT receiver on board SOFIA. We have detected the three hyperfine structure components of the 2THz frequency transition from its ground-state toward four high-mass star-forming regions and determine 13CH column densities. The ubiquity of molecules containing carbon in the ISM has turned the determination of the ratio between the abundances of carbon's two stable isotopes, 12C/13C, into a cornerstone for Galactic chemical evolution studies. Whilst displaying a rising gradient with Galactocentric distance, this ratio, when measured using observations of different molecules (CO, H2CO, and others) shows systematic variations depending on the tracer used. These observed inconsistencies may arise from optical depth effects, chemical fractionation or isotope-selective photo-dissociation. Formed from C+ either via UV-driven or turbulence-driven chemistry, CH reflects the fractionation of C+, and does not show any significant fractionation effects unlike other molecules previously used to determine the 12C/13C isotopic ratio which make it an ideal tracer for the 12C/13C ratio throughout the Galaxy. Therefore, by comparing the derived column densities of 13CH with previously obtained SOFIA data of the corresponding transitions of the main isotopologue 12CH, we derive 12C/13C isotopic ratios toward Sgr B2(M), G34.26+0.15, W49(N) and W51E. Adding our values derived from 12/13CH to previous calculations of the Galactic isotopic gradient we derive a revised value of 12C/13C = 5.85(0.50)R_GC + 15.03(3.40).

Technik wird in unserer Gesellschaft noch immer mit Männlichkeit assoziiert. Das Bild eines Mannes, der mit einer schweren Bohrmaschine arbeitet, erscheint uns vertrauter als das einer Frau, die dieselbe Tätigkeit ausführt. Derartige Repräsentationen von Technik und Geschlecht werden auch von den Medien verbreitet und könnten so bereits Mädchen und jungen Frauen den Zugang zu Technik erschweren. Digitalisierte Medienwelten bieten allerdings die Möglichkeit, neue Technik-Bilder zu entwerfen und dominante Vorstellungen dadurch zu verschieben. Hier könnten Öffentlichkeiten für Mädchen und Frauen entstehen, die eine Selbstverständigung über technische Interessen und damit einhergehend eine Erfahrung von Kompetenz vermitteln könnten. Anhand von fünf Gruppendiskussionen mit 12- bis 15-jährigen Gymnasiastinnen wurden deren Technikverständnis, deren Nutzung digitaler Medien zu Technikthemen, vor allem aber auch deren Ideen zu einer für sie attraktiven Vermittlung von Technikthemen erfragt. Dabei wurden insbesondere die Vorteile einer symmetrischen Kommunikation im Netz deutlich.

The aim of this thesis is to investigate and optimize the camera system which is used for Filtered Rayleigh Scattering (FRS) measurement systems. Theoretical considerations about the integration of interference filters explain state-of-the-art accuracy limitations. Based on that promising modifications of the established FRS system are presented: test results indicate that frequency fringes - artifacts distorting FRS scans - are minimized by positioning the spectral bandpass filter between camera and first lens. As a tradeoff, the signal level decreases by 70 % to 75% depending on the beam path through the molecular filter. Furthermore, reference measurements without a bandpass filter account for a non-negligible iodine fluorescence background of about 1% of typical signal levels. All things considered following these results FRS systems can now be systematically optimized towards specific measurement tasks.

Dieses Lehrbuch behandelt zunächst zentrale Themen der klassischen Theoretischen Informatik und führt darauf aufbauend in die Grundlagen der Algorithmischen Informationstheorie ein.

For robots acting in human-centered environments, the ability to improve based on experience is essential for reliable and adaptive operation; however, particularly in the context of robot failure analysis, experience-based improvement is only useful if robots are also able to reason about and explain the decisions they make during execution. In this paper, we describe and analyse a representation of execution-specific knowledge that combines (i) a relational model in the form of qualitative attributes that describe the conditions under which actions can be executed successfully and (ii) a continuous model in the form of a Gaussian process that can be used for generating parameters for action execution, but also for evaluating the expected execution success given a particular action parameterisation. The proposed representation is based on prior, modelled knowledge about actions and is combined with a learning process that is supervised by a teacher. We analyse the benefits of this representation in the context of two actions – grasping handles and pulling an object on a table – such that the experiments demonstrate that the joint relational-continuous model allows a robot to improve its execution based on experience, while reducing the severity of failures experienced during execution.

Any political phenomenon can only be properly understood in its broader con-text. Questions of international cooperation are thus necessarily framed by his-torical processes and relations of power. We therefore start our first discussion with an examination of the global ‘status quo’ and embed the topic of this pub-lication, ODA graduation, into the shifting world order, analysing current roles and settings in international relations and identifying changes in positions, sta-tus and categories. What are the overarching issues determining world politics and who are the old and the new actors driving them? What is the impact of these global shifts on international cooperation, especially development coop-eration? Of what relevance are roles, status and categories and what is the im-pact of changes in positions and relations? What challenges face multilateralism and what ways exist to maintain and renew strategic partnerships and shared values?

Solving differential-algebraic equations (DAEs) efficiently by means of appropriate numerical schemes for time-integration is an ongoing topic in applied mathematics. In this context, especially when considering large systems that occur with respect to many fields of practical application effective computation becomes relevant. In particular, corresponding examples are given when having to simulate network structures that consider transport of fluid and gas or electrical circuits. Due to the stiffness properties of DAEs, time-integration of such problems generally demands for implicit strategies. Among the schemes that prove to be an adequate choice are linearly implicit Rung-Kutta methods in the form of Rosenbrock-Wanner (ROW) schemes. Compared to fully implicit methods, they are easy to implement and avoid the solution of non-linear equations by including Jacobian information within their formulation. However, Jacobian calculations are a costly operation. Hence, necessity of having to compute the exact Jacobian with every successful time-step proves to be a considerable drawback. To overcome this drawback, a ROW-type method is introduced that allows for non-exact Jacobian entries when solving semi-explicit DAEs of index one. The resulting scheme thus enables to exploit several strategies for saving computational effort. Examples include using partial explicit integration of non-stiff components, utilizing more advantageous sparse Jacobian structures or making use of time-lagged Jacobian information. In fact, due to the property of allowing for non-exact Jacobian expressions, the given scheme can be interpreted as a generalized ROW-type method for DAEs. This is because it covers many different ROW-type schemes known from literature. To derive the order conditions of the ROW-type method introduced, a theory is developed that allows to identify occurring differentials and coefficients graphically by means of rooted trees. Rooted trees for describing numerical methods were originally introduced by J.C. Butcher. They significantly simplify the determination and definition of relevant characteristics because they allow for applying straightforward procedures. In fact, the theory presented combines strategies used to represent ROW-type methods with exact Jacobian for DAEs and ROW-type methods with non-exact Jacobian for ODEs. For this purpose, new types of vertices are considered in order to describe occurring non-exact elementary differentials completely. The resulting theory thus automatically comprises relevant approaches known from literature. As a consequence, it allows to recognize order conditions of familiar methods covered and to identify new conditions. With the theory developed, new sets of coefficients are derived that allow to realize the ROW-type method introduced up to orders two and three. Some of them are constructed based on methods known from literature that satisfy additional conditions for the purpose of avoiding effects of order reduction. It is shown that these methods can be improved by means of the new order conditions derived without having to increase the number of internal stages. Convergence of the resulting methods is analyzed with respect to several academic test problems. Results verify the theory determined and the order conditions found as only schemes satisfying the order conditions predicted preserve their order when using non-exact Jacobian expressions.