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Alkaline methanol oxidation is an important electrochemical process in the design of efficient fuel cells. Typically, a system of ordinary differential equations is used to model the kinetics of this process. The fitting of the parameters of the underlying mathematical model is performed on the basis of different types of experiments, characterizing the fuel cell. In this paper, we describe generic methods for creation of a mathematical model of electrochemical kinetics from a given reaction network, as well as for identification of parameters of this model. We also describe methods for model reduction, based on a combination of steady-state and dynamical descriptions of the process. The methods are tested on a range of experiments, including different concentrations of the reagents and different voltage range.
The general method of topological reduction for the network problems is presented on example of gas transport networks. The method is based on a contraction of series, parallel and tree-like subgraphs for the element equations of quadratic, power law and general monotone dependencies. The method allows to reduce significantly the complexity of the graph and to accelerate the solution procedure for stationary network problems. The method has been tested on a large set of realistic network scenarios. Possible extensions of the method have been described, including triangulated element equations, continuation of the equations at infinity, providing uniqueness of solution, a choice of Newtonian stabilizer for nearly degenerated systems. The method is applicable for various sectors in the field of energetics, including gas networks, water networks, electric networks, as well as for coupling of different sectors.
Computers can help us to trigger our intuition about how to solve a problem. But how does a computer take into account what a user wants and update these triggers? User preferences are hard to model as they are by nature vague, depend on the user’s background and are not always deterministic, changing depending on the context and process under which they were established. We pose that the process of preference discovery should be the object of interest in computer aided design or ideation. The process should be transparent, informative, interactive and intuitive. We formulate Hyper-Pref, a cyclic co-creative process between human and computer, which triggers the user’s intuition about what is possible and is updated according to what the user wants based on their decisions. We combine quality diversity algorithms, a divergent optimization method that can produce many, diverse solutions, with variational autoencoders to both model that diversity as well as the user’s preferences, discovering the preference hypervolume within large search spaces.
Short summary
This dataset accompanies our paper
A. Mitrevski, P. G. Plöger, and G. Lakemeyer, "Representation and Experience-Based Learning of Explainable Models for Robot Action Execution," in Proceedings of the IEEE/RSJ International Conference on Intelligent Robots and Systems (IROS), 2020.
Contents
There are three zip archives included, each of them a dump of a MongoDB database corresponding to one of the three experiments in the paper:
Grasping a drawer handle (handle_drawer_logs.zip)
Grasping a fridge handle (handle_fridge_logs.zip)
Pulling an object (pull_logs.zip)
All three experiments were performed with a Toyota HSR. Only the data necessary for learning the models used in our experiments are included here.
Usage
After unzipping the archives, each database can be restored with the command
mongorestore [directory_name]
This will create a MongoDB database with the name of the directory (handle_drawer_logs, handle_fridge_logs, and pull_logs).
Code for processing the data and model learning can be found in our <a href="https://github.com/alex-mitrevski/explainable-robot-execution-models">GitHub repository.
This dataset contains data from two measurement campaigns in autumn 2018 and summer 2019 that were part of the BMWi project "MetPVNet", and serve as a supplement to the paper "Dynamic model of photovoltaic module temperature as a function of atmospheric conditions", published in the special edition of "Advances in Science and Research", the proceedings of the 19th EMS Annual Meeting: European Conference for Applied Meteorology and Climatology 2019.
Data are resampled to one minute, and include:
PV module temperature
Ambient temperature
Plane-of-array irradiance
Windspeed
Atmospheric thermal emission
The data were used for the dynamic temperature model, as presented in the paper
Modern Monte-Carlo-based rendering systems still suffer from the computational complexity involved in the generation of noise-free images, making it challenging to synthesize interactive previews. We present a framework suited for rendering such previews of static scenes using a caching technique that builds upon a linkless octree. Our approach allows for memory-efficient storage and constant-time lookup to cache diffuse illumination at multiple hitpoints along the traced paths. Non-diffuse surfaces are dealt with in a hybrid way in order to reconstruct view-dependent illumination while maintaining interactive frame rates. By evaluating the visual fidelity against ground truth sequences and by benchmarking, we show that our approach compares well to low-noise path traced results, but with a greatly reduced computational complexity allowing for interactive frame rates. This way, our caching technique provides a useful tool for global illumination previews and multi-view rendering.
Who do you trust: Peers or Technology? A conjoint analysis about computational reputation mechanisms
(2020)
Peer-to-peer sharing platforms are taking over an increasingly important role in the platform economy due to their sustainable business model. By sharing private goods and services, the challenge arises to build trust between peers online mostly without any kind of physical presence. Peer rating has been proven as an important mechanism. In this paper, we explore the concept called Trust Score, a computational rating mechanism adopted from car telematics, which can play a similar role in carsharing. For this purpose, we conducted a conjoint analysis where 77 car owners chose between fictitious user profiles. Our results show that in our experiment the telemetric-based score slightly outperforms the peer rating in the decision process, while the participants perceived the peer rating more helpful in retrospect. Further, we discuss potential benefits with regard to existing shortcomings of user rating, but also various concerns that should be considered in concepts like telemetric-based reputation mechanism that supplements existing trust factors such as user ratings.
The ongoing digitisation in everyday working life means that ever larger amounts of personal data of employees are processed by their employers. This development is particularly problematic with regard to employee data protection and the right to informational self-determination. We strive for the use of company Privacy Dashboards as a means to compensate for missing transparency and control. For conceptual design we use among other things the method of mental models. We present the methodology and first results of our research. We highlight the opportunities that such an approach offers for the user-centred development of Privacy Dashboards.
Carbon capture and storage
(2020)
This Special Report explores the most recent regulatory, political and economic trends and themes arising from CCS technologies and projects to help the reader succeed in this rapidly changing market.
This article explores the opportunities, challenges, as well as the activities of the Chinese governmental and commercial stakeholders to promote cross-border e-commerce trade between China and Africa, based on the classification and correlation analysis of the literature from 2011 to 2019. The results show that the biggest driver for the development of China-Africa cross-border e-commerce trade is the gap between the rapid growth of the African population, especially the middle class, and the limited local capability to satisfy their demand. The rapid development of the internet and mobile internet is another driving factor. The biggest challenge is the last mile delivery of logistics, and online payment issues in Africa. At the macro-level the Chinese government has promoted measures such as infrastructure investment, e-commerce test zones and the establishment of pilot projects. At the firm level, Chinese companies have focused on solving practical micro-level local operational problems such as logistics, online payment, and talent training. The results also show that the referred literature is still in its infancy, mostly theoretical and less practical, and requires more in-depth domain specific analysis in the future.
With the digital transformation, software systems have become an integral part of our society and economy. In every part of our life, software systems are increasingly utilized to, e.g., simplify housework or to optimize business processes. All these applications are connected to the Internet, which already includes millions of software services consumed by billions of people. Applications which process such a magnitude of users and data traffic requires to be highly scalable and are therefore denoted as Ultra Large Scale (ULS) systems. Roy Fielding has defined one of the first approaches which allows designing modern ULS software systems. In his doctoral thesis, Fielding introduced the architectural style Representational State Transfer (REST) which builds the theoretical foundation of the web. At present, the web is considered as the world's largest ULS system. Due to a large number of users and the significance of software for society and the economy, the security of ULS systems is another crucial quality factor besides high scalability.
Due to the use of fossil fuel resources, many environmental problems have been increasingly growing. Thus, the recent research focuses on the use of environment friendly materials from sustainable feedstocks for future fuels, chemicals, fibers and polymers. Lignocellulosic biomass has become the raw material of choice for these new materials. Recently, the research has focused on using lignin as a substitute material in many industrial applications. The antiradical and antimicrobial activity of lignin and lignin-based films are both of great interest for applications such as food packaging additives. DPPH assay was used to determine the antioxidant activity of Kraft lignin compared to Organosolv lignins from different biomasses. The purification procedure of Kraft lignin showed that double-fold selective extraction is the most efficient confirmed by UV-Vis, FTIR, HSQC, 31PNMR, SEC, and XRD. The antioxidant capacity was discussed regarding the biomass source, pulping process, and degree of purification. Lignin obtained from industrial black liquor are compared with beech wood samples: Biomass source influences the DPPH inhibition (softwood > grass) and the TPC (softwood < grass). DPPH inhibition affected by the polarity of the extraction solvent. Following the trend: ethanol > diethylether > acetone. Reduced polydispersity has positive influence on the DPPH inhibition. Storage decreased the DPPH inhibition but increased the TPC values. The DPPH assay was also used to discuss the antiradical activity of HPMC/lignin and HPMC/lignin/chitosan films. In both binary (HPMC/lignin) and ternary (HPMC/lignin/chitosan) systems the 5% addition showed the highest activity and the highest addition had the lowest. Both scavenging activity and antimicrobial activity are dependent on the biomass source; Organosolv of softwood > Kraft of softwood > Organosolv of grass. Lignins and lignin-containing films showed high antimicrobial activities against Gram-positive and Gram-negative bacteria at 35 °C and at low temperatures (0-7 °C). Purification of Kraft lignin has a negative effect on the antimicrobial activity while storage has positive effect. The lignin leaching in the produced films affected the activity positively and the chitosan addition enhances the activity for both Gram-positive and Gram-negative bacteria. Testing the films against food spoilage bacteria that grow at low temperatures revealed the activity of the 30% addition on HPMC/L1 film against both B. thermosphacta and P. fluorescens while L5 was active only against B. thermosphacta. In HPMC/lignin/chitosan films, the 5% addition exhibited activity against both food spoilage bacteria.
Describing the elephant: a foundational model of human needs, motivation, behaviour, and wellbeing
(2020)
Models of basic psychological needs have been present and popular in the academic and lay literature for more than a century yet reviews of needs models show an astonishing lack of consensus. This raises the question of what basic human psychological needs are and if this can be consolidated into a model or framework that can align previous research and empirical study. The authors argue that the lack of consensus arises from researchers describing parts of the proverbial elephant correctly but failing to describe the full elephant. Through redefining what human needs are and matching this to an evolutionary framework we can see broad consensus across needs models and neatly slot constructs and psychological and behavioural theories into this framework. This enables a descriptive model of drives, motives, and well-being that can be simply outlined but refined enough to do justice to the complexities of human behaviour. This also raises some issues of how subjective well-being is and should be measured. Further avenues of research and how to continue building this model and framework are proposed.
Autonomous driving enables new mobility concepts such as shared-autonomous services. Although significant re-search has been done on passenger-car interaction, work on passenger interaction with robo-taxis is still rare. In this paper, we tackle the question of how passengers experience robo-taxis as a service in real-life settings to inform the interaction design. We conducted a Wizard of Oz study with an electric vehicle where the driver was hidden from the passenger to simulate the service experience of a robo-taxi. 10 participants had the opportunity to use the simulated shared-autonomous service in real-life situations for one week. By the week's end, 33 rides were completed and recorded on video. Also, we flanked the study conducting interviews before and after with all participants. The findings provided insights into four design themes that could inform the service design of robo-taxis along the different stages including hailing, pick-up, travel, and drop-off.
For a sustainable development the electricity sector needs to be decarbonized. In 2017 only 54% of the West African households had access to the electrical grid. Thus, renewable sources should play a major role for the development of the power sector in West Africa. Above all, solar power shows highest potential of renewable energy sources. However, it is highly variable, depending on the atmospheric conditions. This study addresses the challenges for a solar based power system in West Africa by analyzing the atmospheric variability of solar power. For this purpose, two aspects are investigated. In the first part, the daily power reduction due to atmospheric aerosols is quantified for different solar power technologies. Meteorological data at six ground-based stations is used to model photovoltaic and parabolic trough power during all mostly clear-sky days in 2006. A radiative transfer model is combined with solar power model. The results show, that the reduction due to aerosols can be up to 79% for photovoltaic and up to 100% for parabolic trough power plants during a major dust outbreak. Frequent dust outbreaks occurring in West Africa would cause frequent blackouts if sufficient storage capacities are not available. On average, aerosols reduce the daily power yields by 13% to 22% for photovoltaic and by 22% to 37% for parabolic troughs. For the second part, long-term atmospheric variability and trends of solar irradiance are analyzed and their impact on photovoltaic yields is examined for West Africa. Based on a 35-year satellite data record (1983 - 2017) the temporal and spatial variability and general trend are depicted for global and direct horizontal irradiances. Furthermore, photovoltaic yields are calculated on a daily basis. They show a strong meridional gradient with highest values of 5 kWh/kWp in the Sahara and Sahel zone and lowest values in southern West Africa (around 4 kWh/kWp). Thereby, the temporal variability is highest in southern West Africa (up to around 18%) and lowest in the Sahara (around 4.5%). This implies the need of a North-South grid development, to feed the increasing demand on the highly populated coast by solar power from the northern parts of West Africa. Additionally, global irradiances show a long-term positive trend (up to +5 W/m²/decade) in the Sahara and a negative trend (up to -5 W/m²/decade) in southern West Africa. If this trend is continuing, the spatial differences in solar power potential will increase in the future. This thesis provides a better understanding of the impact of atmospheric variability on solar power in a challenging environment like West Africa, characterized by the strong influence of the African monsoon. Thereby, the importance of aerosols is pointed out. Furthermore, long-term changes of irradiance are characterized concerning their implications for photovoltaic power.
Turbulent compressible flows are traditionally simulated using explicit Eulerian time integration applied to the Navier-Stokes equations. However, the associated Courant-Friedrichs-Lewy condition severely restricts the maximum time step size. Exploiting the Lagrangian nature of the Boltzmann equation's material derivative, we now introduce a feasible three-dimensional semi-Lagrangian lattice Boltzmann method (SLLBM), which elegantly circumvents this restriction. Previous lattice Boltzmann methods for compressible flows were mostly restricted to two dimensions due to the enormous number of discrete velocities needed in three dimensions. In contrast, this Rapid Communication demonstrates how cubature rules enhance the SLLBM to yield a three-dimensional velocity set with only 45 discrete velocities. Based on simulations of a compressible Taylor-Green vortex we show that the new method accurately captures shocks or shocklets as well as turbulence in 3D without utilizing additional filtering or stabilizing techniques, even when the time step sizes are up to two orders of magnitude larger compared to simulations in the literature. Our new method therefore enables researchers for the first time to study compressible turbulent flows by a fully explicit scheme, whose range of admissible time step sizes is only dictated by physics, while being decoupled from the spatial discretization.
4GREAT is an extension of the German Receiver for Astronomy at Terahertz frequencies (GREAT) operated aboard the Stratospheric Observatory for Infrared Astronomy (SOFIA). The spectrometer comprises four different detector bands and their associated subsystems for simultaneous and fully independent science operation. All detector beams are co-aligned on the sky. The frequency bands of 4GREAT cover 491-635, 890-1090, 1240-1525 and 2490-2590 GHz, respectively. This paper presents the design and characterization of the instrument, and its in-flight performance. 4GREAT saw first light in June 2018, and has been offered to the interested SOFIA communities starting with observing cycle 6.
Fundamental hydrogen storage properties of TiFe-alloy with partial substitution of Fe by Ti and Mn
(2020)
TiFe intermetallic compound has been extensively studied, owing to its low cost, good volumetric hydrogen density, and easy tailoring of hydrogenation thermodynamics by elemental substitution. All these positive aspects make this material promising for large-scale applications of solid-state hydrogen storage. On the other hand, activation and kinetic issues should be amended and the role of elemental substitution should be further understood. This work investigates the thermodynamic changes induced by the variation of Ti content along the homogeneity range of the TiFe phase (Ti:Fe ratio from 1:1 to 1:0.9) and of the substitution of Mn for Fe between 0 and 5 at.%. In all considered alloys, the major phase is TiFe-type together with minor amounts of TiFe2 or \b{eta}-Ti-type and Ti4Fe2O-type at the Ti-poor and rich side of the TiFe phase domain, respectively. Thermodynamic data agree with the available literature but offer here a comprehensive picture of hydrogenation properties over an extended Ti and Mn compositional range. Moreover, it is demonstrated that Ti-rich alloys display enhanced storage capacities, as long as a limited amount of \b{eta}-Ti is formed. Both Mn and Ti substitutions increase the cell parameter by possibly substituting Fe, lowering the plateau pressures and decreasing the hysteresis of the isotherms. A full picture of the dependence of hydrogen storage properties as a function of the composition will be discussed, together with some observed correlations.
Among the celestial bodies in the Solar System, Mars currently represents the main target for the search for life beyond Earth. However, its surface is constantly exposed to high doses of cosmic rays (CRs) that may pose a threat to any biological system. For this reason, investigations into the limits of resistance of life to space relevant radiation is fundamental to speculate on the chance of finding extraterrestrial organisms on Mars. In the present work, as part of the STARLIFE project, the responses of dried colonies of the black fungus Cryomyces antarcticus Culture Collection of Fungi from Extreme Environments (CCFEE) 515 to the exposure to accelerated iron (LET: 200 keV/μm) ions, which mimic part of CRs spectrum, were investigated. Samples were exposed to the iron ions up to 1000 Gy in the presence of Martian regolith analogues. Our results showed an extraordinary resistance of the fungus in terms of survival, recovery of metabolic activity and DNA integrity. These experiments give new insights into the survival probability of possible terrestrial-like life forms on the present or past Martian surface and shallow subsurface environments.