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This paper proposes a new artificial neural network-based maximum power point tracker for photovoltaic application. This tracker significantly improves efficiency of the photovoltaic system with series-connection of photovoltaic modules in non-uniform irradiance on photovoltaic array surfaces. The artificial neural network uses irradiance and temperature sensors to generate the maximum power point reference voltage and employ a classical perturb and observe searching algorithm. The structure of the artificial neural network was obtained by numerical modelling using Matlab/Simulink. The artificial neural network was trained using Bayesian regularisation back-propagation algorithms and demonstrated a good prediction of the maximum power point. Relative number of Vmpp prediction errors in range of ±0.2V is 0.05% based on validation data.