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Hydrogen is a versatile energy carrier. When produced with renewable energy by water splitting, it is a carbon neutral alternative to fossil fuels. The industrialization process of this technology is currently dominated by electrolyzers powered by solar or wind energy. For small scale applications, however, more integrated device designs for water splitting using solar energy might optimize hydrogen production due to lower balance of system costs and a smarter thermal management. Such devices offer the opportunity to thermally couple the solar cell and the electrochemical compartment. In this way, heat losses in the absorber can be turned into an efficiency boost for the device via simultaneously enhancing the catalytic performance of the water splitting reactions, cooling the absorber, and decreasing the ohmic losses.[1,2] However,integrated devices (sometimes also referred to as “artificial leaves”), currently suffer from a lower technology readiness level (TRL) than the completely decoupled approach.
Integrated solar water splitting devices that produce hydrogen without the use of power inverters operate outdoors and are hence exposed to varying weather conditions. As a result, they might sometimes work at non-optimal operation points below or above the maximum power point of the photovoltaic component, which would directly translate into efficiency losses. Up until now, however, no common parameter describing and quantifying this and other real-life operating related losses (e.g. spectral mismatch) exists in the community. Therefore, the annual-hydrogen-yield-climatic-response (AHYCR) ratio is introduced as a figure of merit to evaluate the outdoor performance of integrated solar water splitting devices. This value is defined as the ratio between the real annual hydrogen yield and the theoretical yield assuming the solar-to-hydrogen device efficiency at standard conditions. This parameter is derived for an exemplary system based on state-of-the-art AlGaAs//Si dual-junction solar cells and an anion exchange membrane electrolyzer using hourly resolved climate data from a location in southern California and from reanalysis data of Antarctica. This work will help to evaluate, compare and optimize the climatic response of solar water splitting devices in different climate zones.