Open Access

Background: Coniferous woods (Abies nordmanniana (Stev.) Spach, Abies procera Rehd, Picea abies (L.) H.Karst, and Picea pungens Engelm.) could contain useful secondary metabolites to produce sustainable packaging materials, e.g., by substitution of harmful petrol-based additives in plastic packaging. This study aims to characterise the antioxidant and light-absorbing properties and ingredients of different coniferous wood extracts with regard to different plant fragments and drying conditions. Furthermore, the valorisation of used Christmas trees is evaluated. Methods: Different drying and extraction techniques were applied with the extracts being characterised by determining the total phenolic content (TPC), total antioxidant capacity (TAC), and absorbance in the ultraviolet range (UV). Gas chromatography coupled with mass spectrometry (GC-MS) and an acid–butanol assay (ABA) were used to characterise the extract constituents. Results: All the extracts show a considerably high UV absorbance while interspecies differences did occur. All the fresh and some of the dried biomass extracts reached utilisable TAC and TPC values. A simplified extraction setup for industrial application is evaluated; comparable TAC results could be reached with modifications. Conclusion: Coniferous woods are a promising renewable resource for preparation of sustainable antioxidants and photostabilisers. This particularly applies to Christmas trees used for up to 12 days. After extraction, the biomass can be fully valorised by incorporation in paper packaging.

The development of metals tailored to the metallurgical conditions of laser-based additive manufacturing is crucial to advance the maturity of these materials for their use in structural applications. While efforts in this regard are being carried out around the globe, the use of high strength eutectic alloys have, so far, received minor attention, although previous works showed that rapid solidification techniques can result in ultrafine microstructures with excellent mechanical performance, albeit for small sample sizes. In the present work, a eutectic Ti-32.5Fe alloy has been produced by laser powder bed fusion aiming at exploiting rapid solidification and the capability to produce bulk ultrafine microstructures provided by this processing technique. Process energy densities between 160 J/mm³ and 180 J/mm³ resulted in a dense and crack-free material with an oxygen content of ~ 0.45 wt.% in which a hierarchical microstructure is formed by µm-sized η-Ti4Fe2Ox dendrites embedded in an ultrafine eutectic β-Ti/TiFe matrix. The microstructure was studied three-dimensionally using near-field synchrotron ptychographic X-ray computed tomography with an actual spatial resolution down to 39 nm to analyse the morphology of the eutectic and dendritic structures as well as to quantify their mass density, size and distribution. Inter-lamellar spacings down to ~ 30–50 nm were achieved, revealing the potential of laser-based additive manufacturing to generate microstructures smaller than those obtained by classical rapid solidification techniques for bulk materials. The alloy was deformed at 600 °C under compressive loading up to a strain of ~ 30% without damage formation, resulting in a compressive yield stress of ~ 800 MPa. This study provides a first demonstration of the feasibility to produce eutectic Ti-Fe alloys with ultrafine microstructures by laser powder bed fusion that are suitable for structural applications at elevated temperature.

Das Ziel von zwei öffentlich geförderten FE-Projekten ist eine verbesserte Material- und Ressourceneffizienz für konventionell blasgeformte Artikel. Die FE-Projekte RedPro (Reduzierung von Prototypen in der Blasformbranche) und MatRes (Material- und Ressourceneffizienz für blasgeformte Kunststoffhohlkörper) sind jeweils Gemeinschaftsforschungsvorhaben der Dr. Reinold Hagen Stiftung, der Hochschule Bonn-Rhein-Sieg und mehreren Industrieunternehmen. Thematisch unterscheiden sich die zwei FE-Projekte dadurch, dass im laufenden Projekt RedPro schwerpunktmäßig das Schrumpf- und Verzugsverhalten von technischen Blasformteilen und im beantragten FE-Projekt MatRes die integrative Optimierung in Anwendung auf Verpackungsartikel untersucht werden. Für beide Produktgruppen soll durch die Neu- und Weiterentwicklung von bestehenden Simulationsmodellen das Produktverhalten auch ohne physikalische Prototypen mit hinreichender Genauigkeit vorhergesagt werden. Im Ergebnis entsprechen die Artikel in Performance und Designansprüchen bestehenden oder vergleichbaren Artikeln, allerdings bei deutlich geringerem Gewicht.

Since thermal barrier coatings (TBCs) for turbine blades suffer from bond coat oxidation and sintering of the ceramic top coat during service, quantification of TBC degradation by non destructive evaluation methods (NDE) is essential. IN617 substrates with standard NiCoCrAlY/PYSZ EBPVD TBCs were annealed at 1100 °C and measured by impedance spectroscopy. Parameters such as phase angle, total impedance, real and imaginary part were analyzed. To clearly separate bond coat oxidation from aging of the zirconia, freestanding ceramic top coats and ceramic free samples were analyzed as well. A straight correlation between the changes in the impedance spectra and the measured thickness of the thermally grown oxide was found.